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A Transport coefficient can be expressed via a Green-Kubo relation: :, where is an observable occurring in a perturbed Hamiltonian, is an ensemble average and the dot above the A denotes the time derivative.〔Water in Biology, Chemistry, and Physics: Experimental Overviews and Computational Methodologies, G. Wilse Robinson, ISBN 9789810224516, p. 80, (Google Books )〕 For times that are greater than the correlation time of the fluctuations of the observable the transport coefficient obeys a generalized Einstein relation: : == Examples == * Diffusion constant, relates the flux of particles with the negative gradient of the concentration (see Fick's laws of diffusion) * Heat transport coefficient * Mass transport coefficient * Shear Viscosity * Electrical conductivity 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「transport coefficient」の詳細全文を読む スポンサード リンク
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